NEET | Chemistry | Some Basic Concept of Chemistry | Question with explanation | Previous Year Questions


Chemistry

Some Basic Concepts of Chemistry

 


1.     The number of moles of hydrogen molecules required to produce 20 moles of ammonia through Haber's process is

(a) 40                   (b) 10

(c) 20                   (d) 30

(NEET 2019)

Ans - (d)

2.        The density of 2 M aqueous solution of NaOH is 1.28 g/cm3 . The molality of the solution is (Given that molecular mass of NaOH = 40 g mol-1]

(a) 1.20 m          (b) 1.56 m

(c) 1.67 m          (d) 1.32 m

(Odisha NEET 2019)

Ans. (c)

3.        A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H2SO4 The evolved gaseous mixture is passed through KOH pellets. Weight (in g) of the remaining product at STP will be

(a) 1.4                (b) 3.0

(c) 2.8                (d) 4.4

(NEET 2018)

Ans – (c)

4.     In which case is number of molecules of water maximum?

(a) 18 mL of water

(b) 0.18 g of water

(c) 0.00224 L of water vapours at 1 atm and 273 K (d) 10-3 mol of water

(NEET 2018)

Ans – (a)

5.     Suppose the elements X and Y combine to form two compounds XY2 and X3Y2.  When 0.1 mole of XY2 weighs 10 g and 0.05 mole of X3Y2 weighs 9g, the atomic weights of X and Y are

(a) 40,30

(b) 60, 40

(c) 20, 30

(d) 30, 20

(NEET-II 2016)

Ans. (a)

6.        What is the mass of the precipitate formed when 50 mL of 16.9% solution of AgNO, is mixed with 50 mL of 5.8% NaCl solution? (Ag=107.8, N=14,O=16, Na = 23, Cl = 35.5)

(a) 3.5g              (b) 7g

(c) 14g               (d) 28 g

(2015)

Ans – (b)

7. If Avogadro number NĄ, is changed from 6.022 x 1023 mol-1 to 6.022 x 1020 mol-1 this would change

(a) the mass of one mole of carbon

(b) the ratio of chemical species to each other in a balanced equation

(c) the ratio of elements to each other in a compound

(d) the definition of mass in units of grams.

(2015)

Ans. (a)

8.     The number of water molecules is maximum in

(a) 1.8 gram of water

(b) 18 gram of water

(c) 18 moles of water

(d) 18 molecules of water. 

(2015)

Ans – (c)

9.     A mixture of gases contains H2 and O2 gases in the ratio of 1:4 (w/w). What is the molar ratio of the two gases in the mixture?

(a) 16:1             (b) 2:1

(c) 1:4                (d) 4:1

(2015, Cancelled)

Ans – (d)

10.  Equal masses of H, O, and methane have been taken in a container of volume V at temperature 27°C in identical conditions. The ratio of the volumes of gases H,:0, : methane would be

(a) 8:16:1

(b) 16:8:1

(c) 16:1:2

(d) 8:1:2

(2014)

Ans – (d)

11.  When 22.4 litres of H2(g) is mixed with 11.2 litres of Cl2(g) , each at S.T.P, the moles of HCl(g) formed is equal to

(a) 1 mol of HCl(g)

(b) 2 mol of HCl(g)

 (c) 0.5 mol of HCl(g)

(d) 1.5 mol of HCl(g)

(2014)

Ans – (a)

12.     1.0 g of magnesium is burnt with 0.56 g O2  in a closed vessel. Which reactant is left in excess and how much? (At. wt. Mg = 24,0 = 16)

(a) Mg, 0.16 g

(b) 0, 0.16 g

(c) Mg, 0.44 g

(d) 0, 0.28 g

(2014)

Ans – (a)

13.  6.02 x 1020 molecules of urea are present in 100 mL of its solution. The concentration of solution is (a) 0.001 M

(b) 0.1 M

(c) 0.02 M

(d) 0.01 M

(NEET 2013)

Ans – (d)

14.  In an experiment it showed that 10 mL of 0.05 M solution of chloride required 10 mL of 0.1 M solution of AgNO3 which of the following will be the formula of the chloride (X stands for the symbol of the element other than chlorine)?

(a) X2Cl2

(b) XCl2

(c) XCI4

(d) X2Cl

(Karnataka NEET 2013)

Ans – (b)

15.  Which has the maximum number of molecules among the following?

(a) 44 g CO2

(b) 48 g O3

(c) 8 g H2

(d) 64 g SO2

(Mains 2011)

Ans – (c)

16.  The number of atoms in 0.1 mol of a triatomic gas is (NA = 6.02 x 1023 mol-1 )

(a) 6.026 x 1022

(b) 1.806 x 1023

(c) 3.600 x 1023

(d) 1.800 x 1022

(2010)

Ans – (b)

17.  25.3 g of sodium carbonate, Na2CO3 is dissolved in enough water to make 250 mL of solution. If sodium carbonate dissociates completely, molar concentration of sodium ion, Na+ and carbonate ions, CO32- respectively

(Molar mass of Na2CO3 = 106 g mol-1)

(a) 0.955 M and 1.910 M

(b) 1.910 M and 0.955 M

(c) 1.90 M and 1.910 M

(d) 0.477 M and 0.477 M

(2010)

Ans – (b)

18.     10 g of hydrogen and 64 g of oxygen were filled in a steel vessel and exploded. Amount of water produced in this reaction will be

 (a) 3 mol         

(b) 4 mol

(c) 1 mol          

(d) 2 mol

(2009)

Ans – (b)

19.  What volume of oxygen gas (O2) measured at 0°C and 1 atm, is needed to burn completely 1 L of propane gas (C3H8) measured under the same conditions?

(a) 5L                 (b) 10 L

(c) 7L                 (d) 6 L

(2008)

Ans – (a)

20.     How many moles of lead (II) chloride will be formed from a reaction between 6.5 g of PbO and 3.2 g HCl?

(a) 0.011         (b) 0.029

(c) 0.044         (d)0.333 

(2008)

Ans – (b)

21.  An organic compound contains carbon, hydrogen and oxygen. Its elemental analysis gave C, 38.71% and H, 9.67%. The empirical formula of the compound would be

(a) CHO             (b) CH4O

(c) CH3O            (d) CH2O

 (2008)

Ans – (c)

22.  An element, X has the following isotopic composition : 200X : 90% 99X: 8.0% 202X : 2.0% The weighted average atomic mass of the naturally occurring element X is closest to

        (a) 201 amu        (b) 202 amu

        (c) 199 amu         (d) 200 amu 

        (2007)

        Ans – (d)

23.  The maximum number of molecules is present in

        (a) 15 L of H2 gas at STP

        (b) 5 L of N2 gas at STP

        (c) 0.5 g of H2 gas

        (d) 10 g of O2 gas.

(2004)

Ans – (a)

24.  Which has maximum molecules?

(a) 7 g N2         

(b) 2 g H2

(c) 16 g NO2

(d) 16 g O2

(2002)

Ans – (b)

25.     Percentage of Se in peroxidase anhydrous enzyme is 0.5% by weight (at. wt. = 78.4) then minimum molecular weight of peroxidase anhydrous enzyme is

(a) 1.568 x 104

(b) 1.568 x 103

(c) 15.68

(d) 2.136 x 104

(2001)

Ans – (a)

26.  Molarity of liquid HCl, if density of solution is 1.17 g/cc is

 (a) 36.5                        (b) 18.25

(c) 32.05                       (d) 42.10

(2001)

Ans- (c)

27.  Specific volume of cylindrical virus particle is 6.02 x 10-2 cc/g whose radius and length are 7 Å and 10 Å respectively. If NA = 6.02 x 1023, find molecular weight of virus.

(a) 15.4 kg/mol

(b) 1.54 x 104 kg/mol

(c) 3.08 x 104 kg/mol

(d) 3.08 x 102 kg/mol

(2001)

Ans – (a)

28.     Volume of CO2 obtained by the complete decomposition of 9.85 g of BaCO3 is

(a) 2.24 L        (b) 1.12 L

(c) 0.84 L        (d)0.56L (2000)

Ans – (b)

29.  Oxidation numbers of A, B, C are +2, +5 and -2 respectively. Possible formula of compound is

(a) A2(BC)2

(b) A3(BC4)2

(c) A2(BC3)2

(d) A3(B2C)2

(2000)

Ans – (b)

30.  The number of atoms in 4.25 g of NH3 is approximately 

        (a) 4 x 1023

(b) 2 x 1023

(c) 1 x 1023

(d) 6 x 1023

(1999)

Ans – (d)

31.     Given the numbers : 161 cm, 0.161 cm, 0.0161 cm. The number of significant figures for the three numbers is

(a) 3, 3 and 4 respectively 

(b) 3, 4 and 4 respectively 

(c) 3, 4 and 5 respectively

(d) 3, 3 and 3 respectively. 

(1998)

Ans – (d)

32.  Haemoglobin contains 0.334% of iron by weight. The molecular weight of haemoglobin is approximately 67200. The number of iron atoms (Atomic weight of Fe is 56) present in one molecule of haemoglobin is

(a) 4        (b) 6

(c) 3        (d) 2

(1998)

33.        In the reaction,

4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(l)

when 1 mole of ammonia and 1 mole of O2 are made to react to completion :

(a) all the oxygen will be consumed

(b) 1.0 mole of NO will be produced

(c) 1.0 mole of H2O is produced

(d) all the ammonia will be consumed.

(1998)

Ans – (a)

34.  0.24 g of a volatile gas, upon vaporisation, gives 45 mL vapour at NTP. What will be the vapour density of the substance? (Density of H, = 0.089 g/L)

(a) 95.93            (b) 59.93

(c) 95.39           (d) 5.993

(1996)

Ans - (b)

35.  The amount of zinc required to produce 224 mL of H2 at STP on treatment with dilute H2SO4 will be

(a) 65 g  

(b) 0.065 g

(c) 0.65 g           

(d) 6.5 g

(1996)

Ans – (c)

36.  The dimensions of pressure are the same as that of

(a) force per unit volume

(b) energy per unit volume (c) force

(d) energy

(1995)

Ans – (b)

37.  The number of moles of oxygen in one litre of air containing 21% oxygen by volume, under standard conditions, is

(a) 0.0093 mol

(b) 2.10 mol

    (c) 0.186 mol

    (d) 0.21 mol.

    (1995)

    Ans – (a)

38.     The total number of valence electrons in 4.2 g of Nion is (NA is the Avogadro's number)

(a) 2.1 NA

(b) 4.2 NA

(c) 1.6 NA

(d) 3.2 N.

(1994)

Ans – (c)

39.  A 5 molar solution of H2SO4 is diluted from 1 litre to a volume of 10 litres, the normality of the solution will be

(a) IN     (b) 0.1 N

(c) 5N     (d) 0.5 N

(1991)

Ans – (a)

40.  The number of gram molecules of oxygen in 6.02 x 1024 CO molecules is

(a) 10 g molecules

 (b) 5 g molecules

(c) lg molecules

(d) 0.5 g molecules.

(1990)

Ans – (b)

41.  Boron has two stable isotopes, 10B(19%) and 11B(81%). Calculate average at. wt. of boron in the periodic table.

(a) 10.8                         (b) 10.2

(c) 11.2                          (d) 10.0

(1990)

Ans – (a)

42.  The molecular weight of o, and so, are 32 and 64 respectively. At 15°C and 150 mm Hg pressure, one litre of O2 'N’ molecules. The number of mol two litres of So, under the same co of temperature and pressure will

(a) N/2              (b) N

(c) 2 N                (d) 4 N

(1990)

Ans – (c)

 

43.   A metal oxide has the formula Z2O3. It can be reduced by hydrogen to give free and water. 0.1596 g of the metal oxide requires 6 mg of hydrogen for complete reduction. The atomic weight of the metal is  (a) 27.9                         (b) 159.6

(c) 79.8              (d) 55.8

(1989)

Ans – (d)

44.  Ratio of Cp and Cv of a gas 'X' is number of atoms of the gas 'X' pr 11.2 litres of it at NTP will be

(a) 6.02 x 1023

(b) 1.2 x 1023

(c) 3.01 x 1023

(d) 2.01 x 1023

(1989)

Ans – (d)

45.  What is the weight of oxygen for the complete combustion of ethylene?

(a) 2.8 kg          (b) 6.4 kg

(c) 9.6 kg          (d) 96 kg

(1989)

Ans – (c)

46.     The number of oxygen atoms in 4.4 g of CO2 is

(a) 1.2 x 1023

(b) 6 x 1022

(c) 6 x 1023

(d) 12 x 1023

(1989)

Ans – (a)

47.  At S.T.P. the density of CCI, vapour in g/L will be nearest to

(a) 6.87     (b) 3.42

(c) 10.26    (d) 4.57

(1988)

Ans (a)

48.  One litre hard water contains 12.00 mg Mg2+ Milli-equivalents of washing soda required to remove its hardness is

(a) 1       

(b) 12.16

(c) 1x 10-3

(d) 12.16 x 10-3

(1988)

Ans – (a)

49.  1 cc N2O at NTP contains

(a) (1.8/22.4) x1022 atoms

(b) (6.02/22400) x 1023 molecules

 (c) (1.32/224) x 1023 electrons

 (d) all of the above.

(1988)

Ans – (d)



Explanation


1.       (d)

Haber's process,

N2 + 3H2 → 2NH2

2 moles of NH2 are formed by 3 moles of H2

20 moles of NH3 will be formed by 30 moles of H.

2.     (c)

Density = 1.28 g/cc,

Conc. of solution = 2 M

Molar mass of NaOH = 40 g mol-1

Volume of solution = 1 L = 1000 mL

Mass of solution = d x V

 = 1280 g

Mass of solute = n x Molar mass = 2 x 40 = 80 g

Mass of solvent = (1280 – 80) g = 1200 g

Number of moles of solute

=  (80/40) = 2

Molality = (2 x 1000)/1200

= 1.67 m

3.        (c)

      

H2O absorbed by H2SO4 Gaseous mixture (containing CO and CO2) when passed through KOH pellets, CO2 gets absorbed.

Moles of CO left (unabsorbed)  

Mass of CO=moles x molar mass =   

4.        (a)

Mass of water = Vxd=18x1 = 18 g

Molecules of water = mole x NA = (18/18) NA = NA

(b)

Molecules of water = mole x NA = (0.18/18) NA =10-2 NA

 (c)

Moles of water

= (0.00224/22.4) = 10-4

Molecules of water = mole x NA = 10-4 NA

(d)

Molecules of water = mole x NA = 10-2 NA

5.        (a)

Let atomic weight of element X is x and that of element Y is y. For XY2, n = w/Mol. wt.

0.1 = 10/(x + 2y)

x  + 2y = (10/0.1) = 100   …(i)

For X3Y2, n = w/Mol. wt.

0.05 = 9/(3x + 2y)

3x + 2y = (9/0.05) = 180   …(ii)

On solving equations (i) and (ii), we get y = 30

x + 2(30) = 100

 x= 100 - 60 = 40

6.        (b)

16.9% solution of AgNO3 means 16.9 g of AgNO3 in 100 mL of solution. 16.9 g of AgNO3 in 100 mL solution

= 8.45 g of AgNO3 in 50 mL solution.

Similarly, 5.8 g of NaCl in 100 mL solution = 2.9 g of NaCl in 50 mL solution.

The reaction can be represented as:


     

     Mass of AgCl precipitated

    = 0.049 x 143.3

    = 7.02 =  7 g

7.        (a)

Mass of 1 mol (6.022 x 1023 atoms) of carbon = 12 g

If Avogadro number is changed to 6.022 x 1020 atoms then mass of 1 mol of carbon  = (12 x 6.022 x 1020)/

(6.022 x 1023) = 12 x 10-3g

8.        (c)

1.8 gram of water = (6.023 x 1023 x 1.8) / (18)

= 6.023 x 1022 molecules

18 gram of water = 6.023 x 1023 molecules 18 moles of water

= 18 x 6.023 x 1023 molecules

9.     (d)

Number of moles of H2 = (1/2)

Number of moles of O2 = (4/32)

Hence, molar ratio

= (1/2) : (4/32) = 4 : 1

10.   (c)

According to Avogadro's hypothesis, ratio of the volumes of gases will be equal to the ratio of their no. of moles.

So, no. of moles

= Mass/Mol. Mass


So, the ratio is

11.   (a)

1 mole = 22.4 litres at S.T.P.

Here, Cl2 is limiting reagent. So, 1 mole of HCl(g) is formed.

12.   (a)

Here, O2 is limiting reagent.

Mass of Mg left in excess = 0.0066 x 24 = 0.16 g

13.      (d)

Moles of urea

= (6.02 x 1020)/(6.02 x 1023)

=0.001

Concentration of solution

= (0.001 x 100) x 1000

= 0.01 M

14.   (b)

Millimoles of solution of chloride

= 0.05 x 10 = 0.5

Millimoles of AgNO3 solution

 = 10 x 0.1 = 1

So, the millimoles of AgNO3 are double than the chloride solution.

XCl2 + 2AgNO3 → 2AgCl + X(NO3)2

15.   (c)

8 g H2 has 4 moles while the others has 1 mole each.

16.   (b)

No. of atoms

= NA x No. of moles x 3

= 6.023 x 1023 x 0.1 x 3

= 1.806 x 1023

17.   (b)

Given that molar mass of

Na2CO3 = 106 g

Molarity of solution

 = (25.3 x 1000)/(106 x 250)

= 0.955 M

Na2CO3 → 2Na+ + CO32-

[Na+] = 2 [Na2CO3)

= 2 x 0.955 = 1.910 M

[CO32-] = [Na2CO3] = 0.955 M

18.   (b)

H2 + (1/2) O2 →H2O

2g           16g    18 g

1 mol 0.5 mol  1 mol

10 g of H2 = 5 mol and

64 g of O2 = 2 mol

In this reaction, oxygen is the limiting reagent so amount of H2O produced depends on that of O2

 Since 0.5 mol of O2 gives 1 mol H2O

2 mol of O2 will give 4 mol H2O

19.      (a)

C3Hg + 5O2 → 3CO2 + 4H2O

1 vol. 5 vol. 3 vol. 4 vol.

According to the above equation 1 vol. or 1 litre of propane requires to 5 vol. or 5 litre of O2 to burn completely.

20.   (b)

Formation of moles of lead (II) chloride depends upon the no. of moles of PbO which acts as a limiting factor here. So, no. of moles of PbCl2 formed will be equal to the no. of moles of PbO i.e. 0.029.

21.   (c)


22.      (d)

Hence, empirical formula of the compound would be CH3O.

 Average isotopic mass of X

 = (200 x 90+199 8+202 x 2)/

(90+8+2)

= (18000+1592 +404)/(100)

=199.96 a.m.u.

= 200 a.m.u. 100

 23.      (a)

24.   (b)

Number of molecules = moles x NA

Molecules of N2

= (7/14) NA = 0.5 NA

Molecules of H2 = 2NA Molecules of NO2 = 16/46 = 0.35 NA

Molecules of O2 =  0.5 NA

2Gh2 (1g mole H2) contains maximum molecules.

25.   (a)

In peroxidase anhydrous enzyme 0.5% Se is present means, 0.5 g Se is present in 100 g of enzyme. In a molecule of enzyme one Se atom must be present. Hence, 78.4 g Se will be present in

(100/0.5) x 7.84 = 1.568 x 104

26.   (c)

Density = 1.17 g/cc.

1 cc. solution contains 1.17 g of HCI

Molarity

= (1.17 x 1000)/(36.5 x 1)

= 32.05

27.   (a)

Specific volume (vol. of 1 g) of cylindrical virus particle

= 6.02 x 10-2 cc/g

Radius of virus, r = 7 Å

= 7 x 10-8 cm

Volume of virus = πr2l

 = (22/7) x (7x10-8)2 x10x10-8

= 154 x 10-23 cc

wt. of one virus particle

=Volume/ Specific volume

    = (154 x10-23)/ (6.02 x10-2) g

Molecular wt. of virus

= wt. of NA particles

 = (154 x10-23 x 6.02 x 10-23) (6.02x10-2)g/mol

= 15400 g/mol = 15.4 kg/mol

28.   (b)

BaCO3 → BaO + CO2

197.34 g        22.4 L at N.T.P.

9.85 g       (22.4/197.34) x 9.85

= 1.118

  = 9.85 g BaCO3 will produce 1.118 L CO2 at N.T.P. on the complete decomposition.

29.   (b)

In A3(BC4)2,

 (+2) x 3 + 2[+5 +4(-2)]

= +6 + 2 (-3) = 0

Hence, in the compound A3(BC4)2, the oxidation no. of ‘A’, 'B' and ‘C’ are +2, +5 and -2 respectively.

30.    (d)

No. of molecules in 4.25 g NH3 = (4.25/17) x 6.023 x 1023

= 2.5 X 6.023 x 1022

Number of atoms in 4.25 g NH3 = 4 x 2.5 x 6.023 x 1022

= 6.023 x 1023

31.   (d)

Zeros placed left to the number are never significant, therefore the no. of significant figures for the numbers.

161 cm = 0.161 cm and 0.0161 cm are same, i.e., 3

32.   (a)

Quantity of iron in one molecule

= (67200/100) x 0.334

= 224.45 atm

No. of iron atoms in one molecule of haemoglobin

= (224.45 / 56) = 4

33.      (a)

 4NH3(g) +5O2(g) → 4NO(g) + 6H2O(l)

4 mole 5 mole 4 mole 6 mole

 = 1 mole of NH3 requires = 5/4

= 1.25 mole of oxygen while 1 mole of O2 requires =4/5

= 0.8 mole of NH3

Therefore, all oxygen will be consumed.

34.   (b)

Weight of gas = 0.24 g, Volume of gas = 45 mL

= 0.045 litre and density of H2 = 0.089

weight of 45 mL of H2

= density x volume

= 0.089 x 0.045

= 4.005 x 10 g

Therefore, vapour density

= (Weight of certain volume of substance)/ (Weight of same volume of hydrogen)

= 0.24 / (4.005x10-3)

 =59.93

35.               (c)

Zn + H2SO4 → ZnSO4+H2

65                        22400 ml

Since 65 g of zinc reacts to liberate 22400 mL of H2 at STP, therefore amount of zinc needed to produce 224 mL of H2 at STP

=  (65/22400) x 224 = 0.65 g

36.   (b)

Pressure= Force/Area

 Therefore, dimensions of pressure = MLT-2/L2

= ML-1T-2

and dimensions of energy per unit volume  = Energy/volume  

= ML2 T-2/L3 = ML-1T-2

37.   (a)

Volume of oxygen in one litre of air = (21/100) X 1000  

= 210 mL

Therefore, no. of mol

=  (210/22400) = 0.0093 mol

38.   (c)

Each nitrogen atom has 5 valence electrons, therefore total number of electrons in N3- ion is 16. Since the molecular mass of N3 is 42, therefore total number of electrons in 4.2 g of N3- ion

= (4.2/42) x 16 x  NA

=1.6 NA

 39.      (a)

 5 M H2SO4 = 10 N H2SO4

N1V1 = N2V2

=10 × 1 = N2 x 10

= N2 = 1 N

40.   (b)

Avogadro's No.

NA = 6.02 x 1023 molecules  6.02 x 1024 CO molecules

= 10 moles CO

= 10 g atoms of O

= 5 g molecules of O2

41.   (a)

Average atomic mass

= (19x10+81x11)/100

= 10.81

  42.         (c)

If 1 L of one gas contains N molecules, 2 L of any gas under the same conditions will contain 2 N molecules. 

  43.         (d)

Z2O3 + 3H2 → 2Z + 3H2O Valency of metal in Z2O3 = 3 0.1596 g of Z2O3 react with 6 mg of H2

[1 mg = 0.001 g = 10-3 g]

1 g of H2 react with = (0.15965/0.006)

= 26.6 g of Z2O3

 Eq. wt. of Z2O3 = 26.6

Now, Eq. wt. of Z + Eq. wt. of O

= Eq. wt. of  Z + 8 = 26.6

= Eq. wt. of Z= 26.6 - 8

= 18.6

At. wt. of Z = 18.6 x 3 = 55.8

[Eq. wt. = Atomic wt./Valency of metal]

44.   (a)

Here, CP /Cy = 1.4, which shows that the gas is diatomic.

22.4 L at NTP

= 6.02 x 1023 molecules

11.2 L at NTP = 3.01 x 1023 molecules

Since gas is diatomic.

11.2 L at NTP = 6.02 x 1023 atom

45.   (c)

C2H4 +3O2 → 2CO2 + 2H2O

28 g 96 g

For complete combustion

2.8 kg of C2H4 requires

 = (96g/28 g) x2.8 kg of O2

=  (96/28) x2.8x103g

= 9.6 x 103g = 9.6 kg of O2

46.      (a)

1 mol of CO2 = 44 g of CO2 :

4.4 g CO2 = 0.1 mol CO2

= 6 x 1022 molecules

[Since, 1 mole CO2 = 6 x 1023 molecules]

= 2 x 6 x 1022 atoms of O

= 1.2 x 1023 atoms of O

47.      (a)

 Weight of 1 mol CCl4 vapour

= 12 + 4 x 35.5 = 154 g  Density of CCl4 vapour

= (154/22.4) gL-1

= 6.875 gL-1

48.      (a)

Mg2+ + Na2CO3 → MgCO3 + 2Na+

1g eq. of Mg2+ = 12g of Mg2+ = 12000 mg

Now, 1000 millieq. of

Na2 CO3 = 12000 mg of Mg2+ .

1 millieq. of Na2 CO3 = 12 mg of Mg2+

49.      (d)

As we know,

22400 cc of N2O contain 6.02 x 1023 molecules .

1       cc of N2O contain 6.02 x 1023 molecules

Since in N2O molecule there are 3 atoms

1cc N2O = (3x6.02 x 1023)/22400 atoms

= (1.8 x 1022)/224  atoms

No. of electrons in a molecule of

N2O = 7 + 7 + 8 = 22

Hence, no. of electrons

= (6.02 x 1023/22400) x   22 electrons

= (1.32/224) x 1023 electrons


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